We are finding that the feature exciting most end users in Drupal 6 is the lovely new jquery based drag and drop, as seen on the blocks and menu edit pages - we will be quite happy never have to explain the concept of "weights" again. The best news is that you can add this functionality to your own forms for free - and here is how.
Build and theme the form
We are assuming your vaguely familiar with the form API - you can brush up here http://api.drupal.org/api/file/developer/topics/forms_api.html - so we won't go into too much detail here. Essentially...